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1-Novak Djokovic (SRB) v Paul-Henri Mathieu (FRA)
Ryan Harrison (USA) v Santiago Giraldo (COL)
Arnau Brugues-David (ESP) v Feliciano Lopez (ESP)
Viktor Troicki (SRB) v 31-Radek Stepanek (CZE)
20-Sam Querrey (USA) v Daniel Munoz-De La Nava (ESP)
Alex Bogomolov Jr. (RUS) v Brian Baker (USA)
Tobias Kamke (GER) v Flavio Cipolla (ITA)
Cedrik Marcel-Stebe (GER) v 15-Stanislas Wawrinka (SUI)
11-Juan Monaco (ARG) v Andrey Kuznetsov (RUS)
Kevin Anderson (RSA) v Paolo Lorenzi (ITA)
Xavier Malisse (BEL) v Pablo Andujar (ESP)
David Goffin (BEL) v 22-Fernando Verdasco (ESP)
26-Jurgen Melzer (AUT) v Mikhail Kukushkin (KAZ)
Fabio Fognini (ITA) v Roberto Bautista Agut (ESP)
Julian Reister (GER) v Guillaume Rufin (FRA)
Michael Russell (USA) v 5-Tomas Berdych (CZE)
4-David Ferrer (ESP) v Olivier Rochus (BEL)
Ivo Karlovic (CRO) v Tim Smyczek (USA)
John Millman (AUS) v Tatsuma Ito (JPN)
Albert Ramos (ESP) v 28-Marcos Baghdatis (CYP)
23-Mikhail Youzhny (RUS) v Matthew Ebden (AUS)
Evgeny Donskoy (RUS) v Adrian Ungur (ROM)
Maxime Authom (BEL) v Carlos Berlocq (ARG)
Victor Hanescu (ROM) v 16-Kei Nishikori (JPN)
10-Nicolas Almagro (ESP) v Steve Johnson (USA)
Daniel Gimeno-Traver (ESP) v Lukasz Kubot (POL)
Bjorn Phau (GER) v Somdev Devvarman (IND)
Simone Bolelli (ITA) v 24-Jerzy Janowicz (POL)
32-Julien Benneteau (FRA) v Grigor Dimitrov (BUL)
Edouard Roger-Vasselin (FRA) v Ruben Bemelmans (BEL)
Lukas Lacko (SVK) v Gilles Muller (LUX)
Lleyton Hewitt (AUS) v 8-Janko Tipsarevic (SRB)
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